The equilibrium constant Kc is not dimensionless
The equilibrium constant Kc is a fundamental quantity
in solving chemical equilibrium problems.
Many secondary school chemistry textbooks use a dimensionless
concentration fraction, which they usually represent with the
symbol K. Both the dimensionlessness and the symbol
K do not comply with the IUPAC guidelines for a
concentration break. We advocate doing away with a dimensionless
equilibrium constant in secondary education because IUPAC has
defined the obvious equilibrium constant Kc with
concentration units. In the so-called Green Book, IUPAC
defines several equilibrium constants, such as K ,
Kp and Kc .
Of these, only the thermodynamic equilibrium constant K is
a dimensionless quantity, but the equilibrium constants Kp
and Kc are expressed with a unit by the IUPAC definition.
We cannot emphasize enough that K and Kc are two
completely different equilibrium constants (see figure: the
calculated value of both equilibrium constants for the synthesis of
ammonia at 298.15 K).
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